基于硫氮转化的PM2.5生成特征初步研究Preliminary Study on PM2.5 Generation Characteristics Based on the Sulfur and Nitrogen Conversion
张信成,郭利利,李荣杰,何秋生,王新明
摘要(Abstract):
为研究太原盆地相关地区氮硫转化对PM_(2.5)生成的影响,该研究在2019年10月1日至11月9日于太原盆地南段某城市使用颗粒物化学组分监测仪(ACSM)对当地空气质量进行了观测,研究结果表明:采样期PM_(2.5)、SO_2、NO_2平均浓度分别为76.40μg/m~3、40.80μg/m~3、56.03μg/m~3,污染天SO_4~(2-)、NO_3~-和NH_4~+(统称SNA)在颗粒物中占比显著高于清洁天。随着颗粒物浓度的上升,NO_2/SO_2呈降低趋势,NO_3~-/SO_4~(2-)呈现出先升后降,说明污染前期NO_3~-转化占主导地位,而后期SO_4~(2-)转化起着重要作用。采样期间较高的湿度和NH_4~+浓度均有利于二次转化,当湿度大于80%时,硫的转化占主导。该研究可为太原盆地相关城市PM_(2.5)污染防治工作提供参考。
关键词(KeyWords): 颗粒物化学组分监测仪(ACSM);SNA;硫转化率;氮转化率
基金项目(Foundation): 国家自然科学基金(42077201);; 海外及港澳学者合作研究基金(41728008);; 山西省研究生优秀创新项目(2017SY076)
作者(Author): 张信成,郭利利,李荣杰,何秋生,王新明
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